| Home – Away | Score | #1 | #2 | #3 | ||
|---|---|---|---|---|---|---|
| 1 – Cadiz CF vs Villarreal 25/10/2020 – 18:00 GMT+3 – Spain – LaLiga | 0-0 | 1 | 2 | 2 | ||
| 2 – Gijon vs Ponferradina 25/10/2020 – 18:00 GMT+3 – Spain – LaLiga2 | 2-1 | 1 | X | 1 | ||
| 3 – Moreirense vs Maritimo 25/10/2020 – 18:00 GMT+3 – Portugal – Primeira Liga | 2-1 | 1 | 1 | 1 | ||
| 4 – Farense vs Rio Ave 25/10/2020 – 18:00 GMT+3 – Portugal – Primeira Liga | 0-1 | 2 | 2 | 2 | ||
| 5 – Wolfsberger AC vs Rapid Vienna 25/10/2020 – 19:00 GMT+3 – Austria – Tipico Bundesliga | 3-4 | 2 | 2 | 2 | ||
| 6 – Nice vs Lille 25/10/2020 – 19:00 GMT+3 – France – Ligue 1 | 1-1 | 2 | 2 | 2 | ||
| 7 – Werder Bremen vs Hoffenheim 25/10/2020 – 20:00 GMT+3 – Germany – Bundesliga | 1-1 | 1 | 2 | 2 | ||
| 8 – Tenerife vs Espanyol 25/10/2020 – 20:15 GMT+3 – Spain – LaLiga2 | 0-0 | X | 2 | 2 | ||
| 9 – Famalicao vs Boavista 25/10/2020 – 20:30 GMT+3 – Portugal – Primeira Liga | 2-2 | 1 | 1 | X | ||
| 10 – Albacete vs Rayo Vallecano 25/10/2020 – 22:30 GMT+3 – Spain – LaLiga2 | 2-1 | 2 | 2 | 2 | ||
| 11 – Malaga vs Mirandes 25/10/2020 – 22:30 GMT+3 – Spain – LaLiga2 | 1-1 | 1 | 1 | 1 | ||
| 12 – Cremonese vs Brescia 25/10/2020 – 23:00 GMT+3 – Italy – Serie B | Postp | 1 | X | X | ||
| 13 – Guimaraes vs Braga 25/10/2020 – 23:00 GMT+3 – Portugal – Primeira Liga | 0-1 | 2 | 2 | 1 |